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Tuesday, August 20, 2013

Fundamentals of Petroleum Refining-1-upes

Assignment – 1
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Fundamentals of Petroleum Refining

Section A
Write short notes on any four of the following
1.      Crude Oil Distillation Unit
2.      Octane Number
3.      Polypropylene
4.      Amine Treating Unit (ATU)
5.      Oxidation Stability

Section B (30 marks)
(Attempt any three)
1.      Discuss the important milestones in Indian Refining Industry.
2.      “Crude Assay is the determination of properties of various fractions of crude oil.” Explain.
3.      Hydrogen is produced commercially using various technologies. Explain these technologies.
4.      What are the major offsite functions in a Refinery?

Section C (50 marks)
(Attempt all questions. Every question carries 10 marks)
Read the case “Seam Weld failure in petroleum pipeline” and answer the following questions:
Case Study:  Seam Weld failure in petroleum pipeline
There are more than 2.5 million miles of oil and gas pipelines in the United States. These pipelines typically contain longitudinal seam welds in each pipe joint and girth welds that connect the individual joints to form the pipeline. Both types of welds are prone to failure from time independent and/or time dependent failure mechanisms.
Many failure investigations focus on the immediate failure cause; i.e., for metals, the metallurgical or technical aspects of the failure.
While some smaller diameter pipelines are seamless, most pipelines are manufactured by forming flat plate or skelp into a tubular form and completing a longitudinal seam weld. Both submerged arc welding and autogenous welding processes are used for weld completion.
Submerged arc welded line pipe is manufactured by first forming a flat plate or skelp into a tubular shape (can) in a set of presses, followed by weld completion. Prior to forming the can, the edges are typically bevelled. Historically, single submerged arc welding (SSAW) and double submerged arc welded (DSAW) processes have been used but, currently, the DSAW process is the only submerged arc welding process that is approved in API 5L. In SSAW line pipe, the edges are joined by a single pass submerged arc weld made from the outside surface onto a backing shoe located at the ID surface. DSAW line pipe is formed in a similar manner except one pass is made from the OD surface followed by a pass from the ID surface, or vice versa. Filler weld material is used in both processes. One variation of this process is used to produced spiral welded DSAW line pipe; in which skelp is helically wound and welded to produce a spiral weld.
Historically, there have been several different autogenous welding processes for longitudinal seam welds including furnace lap welding, furnace butt welding, electric flash welding (EFW) and electric resistance welding (ERW). ERW currently is the dominant autogenous welding process for pipe manufacturing. ERW line pipe is manufactured by forming plate or skelp into a tubular shape and heating the two adjoining edges with electric current and forcing them together mechanically. An autogenous bond is formed between the molten edges. Upset material at the weld is trimmed on the OD and ID surfaces.
Various types of defects can be produced in these welds and the defects typically are unique to the specific welding procedure. Some of these defects are too small to be detected in the mill and are never an integrity problem for the pipelines. Other defects that are not detected at the mill can fail during the initial hydrostatic test of a pipeline, or grow in service by fatigue, stress corrosion cracking, or other mechanisms, resulting in a service leak or failure. Because of differences in the metallurgy at the weld and the base metal of the pipe, the welds can also be prone to environmentally induced failure mechanisms such as preferential corrosion.
This case study describes a rupture of seam weld during a hydrostatic pressure test. The pipeline that failed was comprised of 16-inch diameter by 0.312-inch wall thickness, API 5L X52 line pipe that contained an ERW longitudinal seam. The pipeline transported refined petroleum products. The maximum operating pressure (MOP) on this line segment was 1,408 psig, which corresponds to 69.4% of the specified minimum yield strength (SMYS). The failure occurred during initial pressurization at a test pressure of 1,390 psig, which corresponds to 98.7% of the MOP and 68.5% of the SMYS. The normal operating pressure at the failure location ranged from 1,000 to 1,100 psig (71.0 to 78.1% of MOP).
The pipeline was installed in 1965 and was externally coated with coal tar. The coating was not intact near the failure. The pipeline had an impressed current cathodic protection system that was commissioned around 1965. This pipeline segment was previously hydrostatically tested in the fall of 1965. The hydrostatic test lasted 24 hours and the maximum pressure was 1,760 psig (125% of MOP and 86.8% of SMYS).
The pipe section was visually examined and photographed in the as-received condition. Transverse base metal and cross weld samples were removed from the pipe section for mechanical testing. Samples for chemical analysis of the steel were removed from the base metal. Magnetic particle inspection (MPI) was performed where the coating was removed to identify defects at or near the seam weld. Transverse metallographic samples were removed from the seam, at and away from the failure origin. The samples were mounted, polished, and light photomicrographs were taken to examine the morphology and steel microstructure. Samples were removed from the failure origin to analyze the morphology of the fracture surface in the scanning electron microscope.
The results of the analysis indicated that the rupture initiated at an ID connected pre-existing hook crack. This and all hook cracks are slightly offset from the bond line of the ERW seam. No evidence of in-service growth by fatigue was found, although the quality of the fractography was poor as a result of corrosion of the fracture surfaces that occurred after the rupture. The tensile properties of the line pipe steel and the steel chemistry were typical of the vintage and grade and met the API 5L specifications in place at the time of manufacture. The microstructure and Charpy toughness properties of the steel also were typical for the vintage and grade. 
Questions:
1.      What could be the immediate failure causes for petroleum pipeline?
2.      Write a short note on submerged arc welded line pipe.
3.      Describe the composition and structure of failed Seam Weld pipeline.
4.      Explain the various autogenous welding processes for longitudinal seam welds.
5.      Analyze the conclusion part of the case study.




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